3,3-Bis(methylsulfanyl)-1-(4-nitrophenyl)prop-2-en-1-one

3,3-Bis(methylsulfanyl)-1-(4-nitrophenyl)prop-2-en-1-one

Blog Article

In the title compound, C11H11NO3S2, the S—Csp2 bonds are shorter [1.746 (3) and 1.750 (2) Å] than the S—CH3 bonds lmtbul [1.794 (3) and 1.806 (3) Å], which we attribute to d–π interactions between the S atoms and the C=C bond.

The 1,1-bis(methylsulfanyl)-3-oxopropylene fragment and the 4-nitrophenyl group are both almost planar, with the largest deviations rembrandt - acquerello stucco from their mean planes being 0.053 (1) and 0.017 (2) Å, respectively.The dihedral angle between the two planes is 35.07 (7)°.

Molecules in the crystal are linked into a three-dimensional network by C—H.S and C—H.O hydrogen bonds.